Ueber isomere Dioxime des Cuminils
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چکیده
منابع مشابه
o-Benzoquinone dioxime
The title compound, C(6)H(6)N(2)O(2), was obtained as a product of an in vitro study of the metabolism of benzofuroxan. The molecule exhibits a amphi configuration of the oxime groups C=N-OH. One oxime group is involved in the formation of a strong intra-molecular O-H⋯N hydrogen bond, while another links mol-ecules into zigzag chains along the c axis via inter-molecular O-H⋯N hydrogen bonds.
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The mol-ecule of the title compound, C(14)H(12)N(2)O(4), lies across a crystallographic inversion centre situated at the mid-point of the C-C intra-annular bond. The mol-ecule is not planar, the dihedral angle between the aromatic rings being 50.1 (1)°. The oxime group is in an E position with respect to the -OH group and forms an intra-molecular O-H⋯N hydrogen bond. In the crystal structure, i...
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ژورنال
عنوان ژورنال: Berichte der deutschen chemischen Gesellschaft
سال: 1890
ISSN: 0365-9496,1099-0682
DOI: 10.1002/cber.18900230262